Trains.com

fumes from chemical products and hot metal containers

2169 views
32 replies
1 rating 2 rating 3 rating 4 rating 5 rating
  • Member since
    June 2002
  • 20,096 posts
Posted by daveklepper on Thursday, August 13, 2020 8:17 AM

Thanks for the informed reply.

  • Member since
    September 2003
  • 21,669 posts
Posted by Overmod on Thursday, August 13, 2020 7:01 AM

daveklepper
Question, which is more likely to set off fire and/or explosions with either firecrackers or ammonium nitrate, smoldering cigarette butts or sparks from welding?

In the case of ammonium nitrate, neither.  The only thing that will work is sustained heating, not because it makes vapor but because it increases temperature  and hence reaction, combined with physical confinement to cause the transition to detonation.

Firecrackers of course require containment to detonate; gunpowders only deflagrate (burn) unless confined.  However, they are initiated with fuses, which are another thing entirely.  A welding spark will of course happily ignite a fuse, even through tissue paper or glassine packaging, and a smoldering butt might be similar to 'punk' used to light firework fuses.  Once you have tens of thousands of fuses lighting fuses, you will have a good cause of sustained fire in other materials, including the tubes that contain the fireworks.

Incidentally, and Wayne has been trained somewhat more extensively on this, many modern military explosives are intentionally 'desensitized' to limit their tendency to detonate when subjected to heat or physical shocks.  As we have noted in other threads, plastic explosive like Semtex make a nifty cooking fuel if you are careful about the high flame temperature...

  • Member since
    June 2002
  • 20,096 posts
Posted by daveklepper on Thursday, August 13, 2020 2:57 AM

Look, my original posting on the deleted thread had nothing about politics but merely presentation of some retired Israeli Colonel's theory about fumes hitting hot metal container insides  causing fire and explosions, a theory that I felt suggested a danger to some chemical railroad shipments.  Because of the URL and the nature of the total message where I read the theory, the whole thread got involved in accusations and politics that had zero to with the real subject matter.

Please don't have this happen again.  Please get back to the subject matter.  Question, which is more likely to set off fire and/or explosions with either firecrakers or amonium-nitrate, smoldering cigarette butts or sparks from welding?

And take discussions on Bryan Smith's and/or Kalmbach policies to the thread where it belongs and your personal email with the deciding authorities.  Thanks!

  • Member since
    May 2005
  • From: S.E. South Dakota
  • 13,569 posts
Posted by Murphy Siding on Wednesday, August 12, 2020 2:38 PM

Flintlock76

 

.....Where I have complained is on threads where politics have been gratuitously injected and don't belong.  I daresay most of us, especially me, come to the Forum as an escape from the world, for a time at least, and don't care to have it following us in here......  

 

 

Thumbs Up I hang out on one railroad forum, two car racing forums, and zero political forums.

Thanks to Chris / CopCarSS for my avatar.

  • Member since
    January 2002
  • From: Canterlot
  • 9,575 posts
Posted by zugmann on Wednesday, August 12, 2020 2:15 PM

Convicted One
I think you need to look at the bigger picture. If the moderators went through and pruned just the content they found objectionable, how would that make you feel if your content was what got pruned?

Pretty much how another website operates.  Don't want to name names, but in a completely random thought, when was the last time the railroads used train orders?

Then again - I'm pretty much used to having my posts go "poof" on here. 

It's been fun.  But it isn't much fun anymore.   Signing off for now. 


  

The opinions expressed here represent my own and not those of my employer, any other railroad, company, or person.t fun any

  • Member since
    January 2002
  • From: Canterlot
  • 9,575 posts
Posted by zugmann on Wednesday, August 12, 2020 2:13 PM

charlie hebdo
It used to be threads were locked,  or locked temporarily while offensive post(s) we're removed. Sometimes warnings to all publically or privately to individuals were given by moderators prior to taking any drastic action.

There was a time we knew who the moderators were, too...

It's been fun.  But it isn't much fun anymore.   Signing off for now. 


  

The opinions expressed here represent my own and not those of my employer, any other railroad, company, or person.t fun any

  • Member since
    April 2007
  • 4,557 posts
Posted by Convicted One on Wednesday, August 12, 2020 1:30 PM

I know....I remember.  (yes, but...etc) just about everybody has some formula by which they carve an exception out of the rules by which they convince themselves that "their" content should not be viewed as a violation. There is an example of this in this very thread. And just to be fair to all, I will include myself as  not blameless in this regard.

Sometimes the military threads here veer into the realm of what I consider "non-productive celebration of death".  It's often a matter of perspective where one group is inconsiderate of the sensitivities of others.   Just because the victor gets to write their version of history does not necessarily mean that their POV is just, or objective.

I think that the current moderation deserves some appreciation for objectivity, which is all we can really hope for.  So, when entire threads go *poof*, at least no faction is being treated with favoritism. I prefer that over the way things used to be long ago...YMMV.

  • Member since
    September 2017
  • 5,636 posts
Posted by charlie hebdo on Wednesday, August 12, 2020 12:43 PM

It used to be threads were locked,  or locked temporarily while offensive post(s) we're removed. Sometimes warnings to all publically or privately to individuals were given by moderators prior to taking any drastic action.

  • Member since
    April 2007
  • 4,557 posts
Posted by Convicted One on Wednesday, August 12, 2020 12:42 PM

charlie hebdo
So the question remains,  who is the person(s) who has sought to delete several entire threads? Someone who likes censorship and hides behind the moderators? In a club like this, and in society as a whole,  we are ALL accountable to each other. Otherwise we have chaos or the need for dictatorial measures for which there is no accountability or recourse or appeal.

I think you need to look at the bigger picture. If the moderators went through and pruned just the content they found objectionable, how would that make you feel if your content was what got pruned?

I'm not thrilled about the deletion of thread(s), but at least by nuking the threads in their entirety, they avoid the blame for "playing favorites".  A lesser of the two evils, IMO.

When they do the things that they do, I just take it as a sign to go on to some other topic.

It is their forum, they have every right to marshal it as they deem fit. 

  • Member since
    January 2019
  • From: Henrico, VA
  • 9,728 posts
Posted by Flintlock76 on Wednesday, August 12, 2020 11:58 AM

charlie hebdo
who is the person(s) who has sought to delete several entire threads?

I don't need to know myself, although I will admit to making complaints, I don't do the "Family Circle" thing of "Not-me" and "Ida Know."

However, IF a thread is deleted completely or locked I WOULD like to hear directly from the moderator as to why.  I do think as a group we're owed that much, especially if were Kalmbach magazine subscribers, three in my case.  We pay the bills after all.  It used to be the case when a thread was locked we were told why, that's the way it's done on the "Model Railroader" Forum.    

  • Member since
    September 2017
  • 5,636 posts
Posted by charlie hebdo on Wednesday, August 12, 2020 11:52 AM

Sorry if I misunderstood you in terms of about which threads you have complained to moderators.  So the question remains,  who is the person(s) who has sought to delete several entire threads? Someone who likes censorship and hides behind the moderators? In a club like this, and in society as a whole,  we are ALL accountable to each other. Otherwise we have chaos or the need for dictatorial measures for which there is no accountability or recourse or appeal. It starts go resemble Stalinist Russia,  where purged leaders were airbrushed out of photos,  as though they had never existed. 

  • Member since
    January 2019
  • From: Henrico, VA
  • 9,728 posts
Posted by Flintlock76 on Wednesday, August 12, 2020 11:29 AM

Re-read my previous post, I didn't complain about the Beirut explosion thread.

Where I have complained is on threads where politics have been gratuitously injected and don't belong.  I daresay most of us, especially me, come to the Forum as an escape from the world, for a time at least, and don't care to have it following us in here.  

Politics in the "Transit" and "Passenger" threads I find perfectly acceptable and understandably so, considering both are subsidized by taxpayers who have every right to a say in how their money is spent. 

I hope that suffices.  Aside from that, with all due respect Charlie I don't work for you, so I answer to you either. 

 

  • Member since
    September 2017
  • 5,636 posts
Posted by charlie hebdo on Wednesday, August 12, 2020 10:51 AM

You've made great contributions to threads that have nothing to do with railroading, such as with airplanes. So it wasn't the off topic guideline.  Nor was the thread political.  So what specific guideline was the impetus for your need to attempt to have free speech curtailed? 

  • Member since
    January 2019
  • From: Henrico, VA
  • 9,728 posts
Posted by Flintlock76 on Wednesday, August 12, 2020 9:57 AM

It wasn't personal abuse directed towards me, I can take whatever's thrown at me, I'm a big boy.  Besides, in my lifetime I've been worked over by churlish amateurs and trained professionals and learned how to deal with it.

WHY I pushed the button is for me to know, and free speech, which I have no problem with as a "small 'd' democrat" had nothing to do with it. 

So don't ask.  Consider it a point to ponder. 

Let's just say my pushing the button was due to a horrendous drift from published Forum guidelines,  and if the moderators aren't paying attention I'll do my best to see that they do. 

At any rate, I didn't complain about the previous Beirut explosion thread, I found it quite interesting and wouldn't have commented myself if I didn't find it so.

As far as threads I did complain about, well I'm not going to hide behind the anonymity of the Internet, if in fact the moderators did  act on my complaints and didn't find out about it themselves. 

  • Member since
    January 2014
  • 8,221 posts
Posted by Euclid on Wednesday, August 12, 2020 9:41 AM

Flintlock76

Well, I hit the "destruct" button on one of them, I just don't remember which one.  Wink

 

What was your objection to the thread that required your request for moderator action?

  • Member since
    September 2017
  • 5,636 posts
Posted by charlie hebdo on Wednesday, August 12, 2020 9:30 AM

Flintlock76

 

 
Euclid
Apparently the report abuse button has been changed into a thread deletion button.

 

It's strictly a "report" button," what the "powers that be" do with the report is up to them.  I got no questions as to "whys" or "wherefores" from any moderators whoever they may be, nor any promise as to any actions that might be taken. 

 

If the topic is not to your liking,  don't look at it.  There was no flaming or abuse whatsoever.   Free speech is part of our American heritage. 

Euclid and I usually disagree,  but we have both always upheld the value of open discussions as long as the language is civil. Heavy-handed censorship is un-American. 

  • Member since
    January 2019
  • From: Henrico, VA
  • 9,728 posts
Posted by Flintlock76 on Wednesday, August 12, 2020 9:27 AM

Euclid
Apparently the report abuse button has been changed into a thread deletion button.

It's strictly a "report" button," what the "powers that be" do with the report is up to them.  I got no questions as to "whys" or "wherefores" from any moderators whoever they may be, nor any promise as to any actions that might be taken. 

  • Member since
    January 2014
  • 8,221 posts
Posted by Euclid on Wednesday, August 12, 2020 9:23 AM

Flintlock76

Well, I hit the "destruct" button on one of them, I just don't remember which one.  Wink

 

Apparently the report abuse button has been changed into a thread deletion button.

 

  • Member since
    January 2019
  • From: Henrico, VA
  • 9,728 posts
Posted by Flintlock76 on Wednesday, August 12, 2020 8:33 AM

Well, I hit the "destruct" button on one of them, I just don't remember which one.  Wink

  • Member since
    September 2017
  • 5,636 posts
Posted by charlie hebdo on Wednesday, August 12, 2020 8:17 AM

daveklepper

Overmod, if you don't need the old threqd, neither do I.  In any casem it is up to the Moderator.  Glad to read your post.

 

Hmm.  You sure are happy that the original thread was deleted.  Did you report the previous thread? 

  • Member since
    June 2002
  • 20,096 posts
Posted by daveklepper on Tuesday, August 11, 2020 10:34 PM

Overmod, if you don't need the old threqd, neither do I.  In any casem it is up to the Moderator.  Glad to read your post.

  • Member since
    September 2017
  • 5,636 posts
Posted by charlie hebdo on Tuesday, August 11, 2020 10:00 PM

Threads used to get locked;  now they are totally removed,  twice in a row. In any case, moderators us usually take action only after receiving abuse reports.  I wonder who felt the need to do that? 

  • Member since
    January 2019
  • 1,686 posts
Posted by Erik_Mag on Tuesday, August 11, 2020 9:47 PM

tree68

 Texas City, West, and now Beirut underline the wisdom of immediate observance of these distances.

IIRC, the quantity involved with West was about one RR carload's worth.

A couple of things come to mind with haulage of AN:
First is separating AN carrying train from petroleum carrying trains.
Second may be a coating on the cars to at least briefly block the heat from a fire and allow enough time for an evacuation.

Storage of AN is more of concern than hauling it.

  • Member since
    December 2001
  • From: Northern New York
  • 25,020 posts
Posted by tree68 on Tuesday, August 11, 2020 9:32 PM

Flintlock76
Probably just an unfortunate series of events that lead to the disaster.  No oversight, no safety inspections, an "It's not my job!" attitude from various and sundry officials, or some baksheesh  to other officials, and there you go.  Boom.

This is my take as well.

LarryWhistling
Resident Microferroequinologist (at least at my house) 
Everyone goes home; Safety begins with you
My Opinion. Standard Disclaimers Apply. No Expiration Date
Come ride the rails with me!
There's one thing about humility - the moment you think you've got it, you've lost it...

  • Member since
    December 2001
  • From: Northern New York
  • 25,020 posts
Posted by tree68 on Tuesday, August 11, 2020 9:29 PM

Overmod
Someone like Tree can, and should, quote us current best practice on fighting fires where ammonium nitrate (or something truly more alarming to me, ammonium perchlorate that might have formed peroxides) might be concerned.

As a first responder (firefighter), I'm going straight to the "Orange Book" once I identify the substance.  Ammonium nitrate (in various forms UN numbers 0222, 1942, 2067, 2071, 2426, and 3375) calls for Guide 140 (except for AN-fuel, which is 113),  and ammonium perchlorate (UN numbers 0402 and 1442) calls for Guide 143.

For fire, the ERG calls for an 800 meter isolation zone, as well as considering evacuation for 800 meters - a half mile.  That's if the container is involved.  If the AN itself is involved, that expands to one mile.

For ANFO, we start at isolation for 1,600 meters (a mile).

The ERG is guidance for about the first 10 minutes.  After that, the Incident Commander should have guidance from other sources as well.

The ideal situation calls for big water (flooding quantities), applied from unmanned devices.  This assumes there is time to set up big water, and that big water is even available. 

Texas City, West, and now Beirut underline the wisdom of immediate observance of these distances.

The ERG is available on-line, and for smart phones.  Railfans might find it interesting to observe and reference the placards they see going by as they watch.

LarryWhistling
Resident Microferroequinologist (at least at my house) 
Everyone goes home; Safety begins with you
My Opinion. Standard Disclaimers Apply. No Expiration Date
Come ride the rails with me!
There's one thing about humility - the moment you think you've got it, you've lost it...

  • Member since
    January 2019
  • From: Henrico, VA
  • 9,728 posts
Posted by Flintlock76 on Tuesday, August 11, 2020 5:00 PM

Convicted One
Personally, I still have my money riding on "sabotage", 

No, I'm not buying the sabotage angle myself, if sabotage caused this they're really going to have to prove it to me.

Probably just an unfortunate series of events that lead to the disaster.  No oversight, no safety inspections, an "It's not my job!" attitude from various and sundry officials, or some baksheesh  to other officials, and there you go.  Boom.

  • Member since
    April 2007
  • 4,557 posts
Posted by Convicted One on Tuesday, August 11, 2020 4:44 PM

PNWRMNM
but the walls of a container, or truck, or boxcar never get anywhere near the autoignition temperature. Of course you need a leak from the container to release any flammable vapors and containers are designed not to leak in normal transportation.

 

It's noteworthy how many people seem to believe that some precautions are "overkill", because accidents only happen to "stupid" people.  Until, that is, a sequence of events, however improbable ....manage to all align at just the most inopportune moment.

I'm not saying the "propaganda" is plausible......but strange things do ocassionally have a knack of happening.  Blindfold

Personally, I still have my money riding on "sabotage",  but perhaps that's  just the tinfoil hatter in me?

  • Member since
    September 2003
  • 21,669 posts
Posted by Overmod on Tuesday, August 11, 2020 4:13 PM

daveklepper
I do suggest, however that the originals thread be reposted with all postings of arguments not related to the technical topic deleted from the thread and then the thread locked.  That way, the technical matters already posted can be referenced for this thread.

No, it's a new topic and very little if anything from the Middle East accident is necessary for a proper and on-point technical discussion.

Ammonium nitrate derives some of its hazard from having the element nitrogen in two different 'valence' states.  It also contains oxygen that when energetically released can support combustion in materials that are 'oxidizable' including carbon and aluminum.  The first peculiar concern is that both decomposition and any subsequent combustion can be greatly accelerated in speed over normal fuel combustion: this is why ANFO readily detonates with good yield.

However, the chemical can also start deflagrating (chemically dissociating with substantial rate of exothermic heat release to sustain or worsen, much as a fire does with regular combustion) and for a number of reasons the rate at which the dissociation speed increases with more and more heating can reach the speed of sound in the local material.  At this point faster burning creates a shock wave causing prompt dissociation, which can propagate at many thousands of feet per second through the remainder of a contiguous mass.  This is the deflagration-to-detonation threshold I mentioned in the dead thread.

Ammonium nitrate is difficult to vaporize, and its vapor is not terrifically dangerous in air.  So having it up against a hot surface is not a 'vapor' danger, and even if it were, a BLEVE is impossible because there is no boiling expansion to generate a fuel-air critical mixture in the presence of good flameholding.

Someone like Tree can, and should, quote us current best practice on fighting fires where ammonium nitrate (or something truly more alarming to me, ammonium perchlorate that might have formed peroxides) might be concerned.

  • Member since
    May 2003
  • From: US
  • 2,593 posts
Posted by PNWRMNM on Tuesday, August 11, 2020 4:13 PM

CO,

The term is autoignition temperature. Most flammable liquids and flammable gasses are in the range of about 800 degrees F. This is low enough that exhaust manifolds can ignite a flammable mixture, but the walls of a container, or truck, or boxcar never get anywhere near the autoignition temperature. Of course you need a leak from the container to release any flammable vapors and containers are designed not to leak in normal transportation.

The notion being promoted is a ghost story/bit of propaganda. Take your choice.

Mac McCulloch

Former Bureau of Explosives Inspector

Join our Community!

Our community is FREE to join. To participate you must either login or register for an account.

Search the Community

Newsletter Sign-Up

By signing up you may also receive occasional reader surveys and special offers from Trains magazine.Please view our privacy policy