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A Remedy to Gas Flaring?

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A Remedy to Gas Flaring?
Posted by SD60MAC9500 on Wednesday, June 24, 2020 9:51 AM
 

As many know the DOT recently issued it's final rule on LNG transport in approved DOT-113 Cryo Tank Cars. This might just be the remedy to gas flaring. According to this reuters article last year alone(for more info on gas flaring check this link out). We vented 493.2 bcf of gas to the atmosphere. Flaring while expensive makes sense for mutliple reasons; lack of pipeline capcity, pressure relief, and maintenance procedures. Yet could this usher in a new traffic source? Imagine instead of flaring waste NG it could be recovered, then piped to a nearby liquificaton facilty for transport to any market.. Food for thought. Coal is dwindling and NG could just be the next boon for the rails.

 
 
 
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Posted by JPS1 on Wednesday, June 24, 2020 10:34 AM
As I understand it, based on my limited knowledge, liquified natural gas is gas that has been cooled down to liquid form for ease and safety of non-pressurized storage or transport.
 
When it is being transported in a railway tank car, what steps are required to keep it in its liquid state?
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Posted by Convicted One on Wednesday, June 24, 2020 11:39 AM

SD60MAC9500
Imagine instead of flaring waste NG it could be recovered, then piped to a nearby liquificaton facilty for transport to any market.. Food for thought. Coal is dwindling and NG could just be the next boon for the rails.

Sounds like a great idea.  But as your  linked story points out, the well operators often consider it "uneconomic" to do the right thing.

So my guess is, so long as we allow "Harvey Hustlebuck" to make that decision, the real creativity will be expended in finding excuses and exemptions.

Wonder if you could get reasonable capacity out or a recovery system that is completely rail borne? Making such a system that is semi portable would no doubt lessen the start up costs?

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Posted by SD60MAC9500 on Wednesday, June 24, 2020 12:40 PM
 

JPS1
As I understand it, based on my limited knowledge, liquified natural gas is gas that has been cooled down to liquid form for ease and safety of non-pressurized storage or transport.
 
When it is being transported in a railway tank car, what steps are required to keep it in its liquid state?
 

 

DOT-113 tank cars like other vessels that carry, or store LNG, are heavily jacketed and insulated to keep the temp roughly -260F. Here's more detailed information. In addition to that here's a study on implementing a simple efficient form of transporting LNG stateside based on Japan's current LNG system of storage, and transport by rail.

 
 
 
 
 
Rahhhhhhhhh!!!!
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Posted by Overmod on Wednesday, June 24, 2020 12:54 PM

Note that the two 'preferred' alternatives being researched at the time were multifunctional catalytic conversion of the flared gas and what is presumably using some if the 'wasted' energy of flaring to perform pyrolysis to higher-value (presumably storable liquid in most cases) products.

I see little opportunity for a rail-borne solution to work effectively in almost any current flaring situation, even in initial delivery of self-contained rigs to the points needed. Likewise periodic collection of 'recovery' products is much better suited to trucks than trains in almost all cases, certainly well past where any manufacturer looking at economies of scale would consider it unless heavily or wholly subsidized, probably moreover for a guaranteed time.  I do not expect to see that happening.

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Posted by Convicted One on Wednesday, June 24, 2020 1:30 PM

Brings two things to mind. All the mindless waste back in the days of the Indiana Gas Boom,..... and those science fiction movies where aliens, after having depleted the resources of their own planets, come looking here for their needs.

At least Indiana got a couple of nice glass bottle and jar plants out of the bargain.Wilted Flower

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Posted by Overmod on Wednesday, June 24, 2020 1:35 PM

Convicted One
. All the mindless waste back in the days of the Indiana Gas Boom...

I knew nothing about this until I first read Middletown (which for the uninitiated is a sociology treatment of Muncie, IN) in the '70s.  In those pre-fracking days natural gas was an expen$ive premium fuel, so the accounts of the flaring and waste were much more striking.

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Posted by GERALD L MCFARLANE JR on Wednesday, June 24, 2020 1:44 PM

Convicted One

Sounds like a great idea.  But as your  linked story points out, the well operators often consider it "uneconomic" to do the right thing.

This problem is solved by it not making it the well operators that would have to do the work, make it the refiners, were a lot of flaring takes place as already. 

If I was a well operator I'd invest in storage facilities, a lot of storage facilities at the well farms.  Enough to not have to flare excess NG, but that's just me(if you need a reason, simple, with storage you always have NG available for spikes in demand and can then fill in for those that don't have the capacity).

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Posted by SD60MAC9500 on Wednesday, June 24, 2020 2:44 PM
 

Convicted One

 

 
SD60MAC9500
Imagine instead of flaring waste NG it could be recovered, then piped to a nearby liquificaton facilty for transport to any market.. Food for thought. Coal is dwindling and NG could just be the next boon for the rails.

 

Sounds like a great idea.  But as your  linked story points out, the well operators often consider it "uneconomic" to do the right thing.

So my guess is, so long as we allow "Harvey Hustlebuck" to make that decision, the real creativity will be expended in finding excuses and exemptions.

Wonder if you could get reasonable capacity out or a recovery system that is completely rail borne? Making such a system that is semi portable would no doubt lessen the start up costs?

 

LNG containers exist, if this traffic would not prefer a tank car. We do have an exisiting IM system that could easily accomodate LNG cans. Though when domestic NG production increases I see the devisement of a system to capture and make economical use of waste NG. Micro-Scale Liquification could be that enabler to make it cost effective.

 
 
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Posted by Overmod on Wednesday, June 24, 2020 2:54 PM

SD60MAC9500
Though when domestic NG production increases I see the devisement of a system to capture and make economical use of waste NG. Micro-Scale Liquification could be that enabler to make it cost effective.

This is interesting to me as it has comparable footprint to reverse-Brayton liquefiers (and has the same modular design for easy 'containerized' transport and pad setup).  I have no firsthand knowledge whether the Micro-Scale system is cheaper to buy or maintain or has better uptime or reliability, and would be interested to learn.

I think, though, that the smaller-scale recovery option of choice is going to involve a variant of BOG management with LN2 (which is relatively easily generated and can itself be boiled off with neither emissions nor carbon penalty from heat exchangers).  Similar small-scale traps perhaps with modern-generation reliquefiers for the nitrogen are probably the best solution for LNG tank cars when those become fully 'homologated' in this country -- I don't really know why such a good idea has seen so much Government foot-dragging.

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Posted by tree68 on Wednesday, June 24, 2020 3:11 PM

Another possible solution is to convert the energy to something more useful, at the site.

Our local regional landfill used to flare off the methane generated by the waste.  There are still signs along the road warning of same.

Now they use the methane to fuel gensets, and sell the electricity to the local utility.   I know of at least one other such arrangement, and I know of an ambulance squad that gets their gas from a nearby landfill (to them) as well.

In addition, one landfill uses the waste heat from the gensets to heat and cool greenhouses in which are grown some one fifth of the tomatoes consumed in NY state.  Our local landfill considered that, but has not moved forward with it.

The only issue the local facility encountered was that the existing power transmission lines could not handle the power they would be generating.  Once that was remedied, it was a go.  

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Posted by Convicted One on Wednesday, June 24, 2020 4:32 PM

tree68
In addition, one landfill uses the waste heat from the gensets to heat and cool greenhouses in which are grown some one fifth of the tomatoes consumed in NY state.

That sounds to me like an elegant solution. .....but then I really like tomatoes.

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Posted by Convicted One on Wednesday, June 24, 2020 5:40 PM

GERALD L MCFARLANE JR
If I was a well operator I'd invest in storage facilities, a lot of storage facilities at the well farms.  Enough to not have to flare excess NG, but that's just me

Well, you've got my vote.

Wonder if it makes any sense for these well operators to diversify with energy intensive subsidiary industries?  Perhaps an adjacent aluminum recycling plant, or a glass recycling plant?

Instead of going to all the trouble to supercool and containerize it, just pump it into a nearby gasometer, and pull process gas from that?

 

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Posted by SD60MAC9500 on Wednesday, June 24, 2020 6:39 PM
 

tree68

Another possible solution is to convert the energy to something more useful, at the site.

Our local regional landfill used to flare off the methane generated by the waste.  There are still signs along the road warning of same.

Now they use the methane to fuel gensets, and sell the electricity to the local utility.   I know of at least one other such arrangement, and I know of an ambulance squad that gets their gas from a nearby landfill (to them) as well.

In addition, one landfill uses the waste heat from the gensets to heat and cool greenhouses in which are grown some one fifth of the tomatoes consumed in NY state.  Our local landfill considered that, but has not moved forward with it.

The only issue the local facility encountered was that the existing power transmission lines could not handle the power they would be generating.  Once that was remedied, it was a go.  

 

I've been following this tech since it's announcement. It's called Tri-Gen check out the video. This would be perfect for landfill gas. 

 
 
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Posted by SD60MAC9500 on Wednesday, June 24, 2020 6:58 PM
 

Overmod

 

 
SD60MAC9500
Though when domestic NG production increases I see the devisement of a system to capture and make economical use of waste NG. Micro-Scale Liquification could be that enabler to make it cost effective.

 

This is interesting to me as it has comparable footprint to reverse-Brayton liquefiers (and has the same modular design for easy 'containerized' transport and pad setup).  I have no firsthand knowledge whether the Micro-Scale system is cheaper to buy or maintain or has better uptime or reliability, and would be interested to learn.

 

I think, though, that the smaller-scale recovery option of choice is going to involve a variant of BOG management with LN2 (which is relatively easily generated and can itself be boiled off with neither emissions nor carbon penalty from heat exchangers).  Similar small-scale traps perhaps with modern-generation reliquefiers for the nitrogen are probably the best solution for LNG tank cars when those become fully 'homologated' in this country -- I don't really know why such a good idea has seen so much Government foot-dragging.

 

Micro-Scale lead times are roughly 60-80 minutes. After setup LNG can begin the process of liquification within 20-30 min. Expected unit output depending on capacity is looking about 10,000-30,000 Gal. per day. Here's another unit on the market by Galileo which uses the BOG system you mentioned above.

 
 
 
 
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Posted by Murphy Siding on Wednesday, June 24, 2020 7:09 PM

Any way to use the gas to make electricity?

Thanks to Chris / CopCarSS for my avatar.

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Posted by Psychot on Wednesday, June 24, 2020 7:17 PM

Widespread flaring has done a number on my home state of North Dakota. That whole problem could have been avoided from the get-go if the governor had had the courage to tell the oil companies at the very beginning of the Bakken play--when oil prices were sky-high--that they could not extract a single drop of oil until the gas byproduct issue was solved. They would have found a way.

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Posted by tree68 on Wednesday, June 24, 2020 8:11 PM

Murphy Siding

Any way to use the gas to make electricity?

See my post about the landfill.

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Posted by Murphy Siding on Wednesday, June 24, 2020 8:44 PM

tree68

 

 
Murphy Siding

Any way to use the gas to make electricity?

 

See my post about the landfill.

 

I see that now. Our landfill pipes the methane to a nearby ethanol plant.

Thanks to Chris / CopCarSS for my avatar.

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Posted by Overmod on Wednesday, June 24, 2020 9:15 PM

Many more problems could have been avoided from the get-go if the governor had had the courage to tell the oil companies at the very beginning of the Bakken play--when oil prices were sky-high--that they could not send a single drop of oil by rail until full degassing was performed.  This would relatively easily have been expanded to likely solution of the actual gas byproduct issue requiring the flaring.

And yes, they would have found a way.

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Posted by MidlandMike on Wednesday, June 24, 2020 9:29 PM

GERALD L MCFARLANE JR

 

 
Convicted One

Sounds like a great idea.  But as your  linked story points out, the well operators often consider it "uneconomic" to do the right thing.

 

 

This problem is solved by it not making it the well operators that would have to do the work, make it the refiners, were a lot of flaring takes place as already. 

If I was a well operator I'd invest in storage facilities, a lot of storage facilities at the well farms.  Enough to not have to flare excess NG, but that's just me(if you need a reason, simple, with storage you always have NG available for spikes in demand and can then fill in for those that don't have the capacity).

 

There are hundreds of thousands of oil & gas wells.  Wells are remote from refinery operations.  Refiners would not be interested.

There is no economical way to store natural gas as a gas in a well production facility.  

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Posted by MidlandMike on Wednesday, June 24, 2020 10:03 PM

Overmod

Many more problems could have been avoided from the get-go if the governor had had the courage to tell the oil companies at the very beginning of the Bakken play--when oil prices were sky-high--that they could not send a single drop of oil by rail until full degassing was performed.  This would relatively easily have been expanded to likely solution of the actual gas byproduct issue requiring the flaring.

And yes, they would have found a way.

 

The degassing oder was issued while the oil prices were still high.  It resulted in more flaring.  The pipeline companies won't build more gas lines until the producers sign take-or-pay contracts, where the producer has to pay for so much line capacity whether he uses it or not.  Gas is usually the first thing to deplete in a new field.  The alternatives suggested in the DOE report will take time to develope.

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Posted by Erik_Mag on Thursday, June 25, 2020 12:20 AM

Convicted One

 Instead of going to all the trouble to supercool and containerize it, just pump it into a nearby gasometer, and pull process gas from that?

 

 

This inspired an even more outlandish idea... Methane is lighter than air and thus could be used as a lifting gas in Zeppelins...

I remember a tour of the low temperature lab at UCB, where the prof mentioned that the campus had its own air liquifying plant. I would imagine that a small scale methane liquification plant would be easier to make due to the higher critical temperature of methane than nitorgen. OTOH, the plant would likely need some cooling water.

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Posted by Bruce Kelly on Thursday, June 25, 2020 8:05 AM

Among the numerous magazine titles which roll off the press and out the bindery door where I work each day is Native Business. Last year, they ran a story (linked below) explaining how the MHA Nation in ND were using flared gas to heat greenhouses through the winter months. Just one of many ways in which this otherwise wasted energy can be put to good and profitable use.

https://www.nativebusinessmag.com/the-mha-nation-wants-to-feed-the-world-in-a-food-sovereignty-revolution/

 

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Posted by Overmod on Thursday, June 25, 2020 8:44 AM

Erik_Mag
This inspired an even more outlandish idea... Methane is lighter than air and thus could be used as a lifting gas in Zeppelins...

Not to take away from the original thinking... but it's been thought about.  Methane requires about 4x the volume of helium at STP for equivalent displacement lift, and of course it can be heated nicely as desired to fairly significant over pressure without having to be vented.  Its flammability and explosive limits are still highly important (and its energy content in a critical-mixture explosion high) but it is nowhere near the devil to handle that hydrogen is.

The thing that has really changed the assisted-lift LTA picture is the impending helium shortage.  He quite simply is too precious to waste in party balloons or P-791s* any more, and hydrogen is a public-relations nonstarter for LTA anywhere near the actual public... I looked into the differential density of some combinations of CH4 with changes in temperature in an inflation-insulated envelope but don't remember the results now (and have no rubber bible and am too lazy to go look the data up; I used -70F as a likely ambient temperature at altitude, which may or may not be relevant to the lower-altitude operations that some of the modern LTA schemes envision.  I encourage someone like Erik who knows his stuff to flesh this out again.)

While we are on unusual uses for light hydrocarbons, I still remember the Mexican butane proposal ... to use it as working fluid in ORC heat engines for distributed power, not as a fuel.

*There will be some who don't recognize what this is.  To put it in perspective for those people, here is the official account with the corporate-anthem background music replaced with something more appropriate.

https://m.youtube.com/watch?v=7SkvM_Q5oQM

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Posted by Electroliner 1935 on Friday, June 26, 2020 12:25 AM

Ah, Methane. Years ago a man I worked with told me a story about something he had done as a young man. I always wanted to try it but never did. Basically, he told me he had inflated balloons with natural gas to where they would rise, put a long string on them, light the end of the string and release them at night. The flame would rise up the string until it reached the baloon and POW, a nice explosion in the sky. Could this be done or was he pulling my leg?

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Posted by Overmod on Friday, June 26, 2020 7:06 AM

Electroliner 1935
The flame would rise up the string until it reached the balloon and POW, a nice explosion in the sky.

i see no part of this that wouldn't work, although the effect of the flame 'popping' the balloon might produce more a 'foof' jet of flame than an explosion.  You might have to treat the string with something to control the burning, or arrange carefully for the flame to 'compromise' the wall of the balloon and persist long enough that the bang of the burst doesn't snuff out the actual ignition.  

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Posted by tree68 on Friday, June 26, 2020 7:14 AM

When balloons fail, they tend to snap back to their original size, which would leave just a mass of the gas in the air.  Without ignition, the gas would just dissipate.  With ignition, the gas would light off, pretty much all at once, causing a nice flash. 

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Posted by Electroliner 1935 on Friday, June 26, 2020 11:39 AM

I've considered that if the gas was mixed with air, it would be more likely to explode, but getting the mix right would be difficult. And more hazardus to the filler. 

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Posted by Overmod on Friday, June 26, 2020 1:13 PM

tree68
When balloons fail, they tend to snap back to their original size, which would leave just a mass of the gas in the air.  Without ignition, the gas would just dissipate.  With ignition, the gas would light off, pretty much all at once, causing a nice flash. 

Tree, you're not thinking about what causes the 'bang' you hear when a balloon pops.  See if you can find a slow-motion picture of a balloon being popped with a pin or projectile with Schlieren imaging that shows motion of the enclosed gas as the envelope tears from the point of failure and the tension in the envelope relaxes.  Consider the effect produced if a non-tearing hole were opened in the envelope ... for example, if the neck of the balloon were pinched as it rose to altitude and then released ... and what the subsequent motion of the gas and turbulent mixing to critical stoich might be.

You may not want to 'pre-carburete' the gas in the balloon as the lifting will be much slower with an admixture of air or, better for the fire effects, oxygen.  Of course warming the balloon may enhance its lifting to "ignition height" and you could do this with an electrical element if desired...

I'm assuming that the fire coming up the string is what causes the balloon to pop, and therefore that effective flame holding is present around some portion of the gas cloud that starts evolving through the tearing hole.  What I'd expect to see is a period of edge combustion until you get a critical mixture and then a quick deflagration (the gas not being physically enclosed, which I recall being a requirement for actual detonation in methane/natural gas explosions just as it is with black powder).  Remember that by the time the flame climbs the long string it will be very tall and luminous as more and more lights off in the effective convection plume, so there may be a sheet of luminous flame (by definition good both as a radiant source and relatively long-lived flameholder geometry) around a considerable arc of the balloon's side when initial burnthrough commences.

MUCH more fun ensues if you load a critical mixture into the balloon and provide an electrically-fired spark gap (with multivibrator coil spark, not make and break or single cap discharge) or better yet a squib charge.  If the initial ignition kernel is close to the center of the balloon you might actually get to detonation pressure before the envelope actually ruptures ... 

Then of course are all the fun things you can do with FAE payloads, with liquid or powder materials.  Here the squib charge is 'cold' so the turbulent mixing of the evolving gas cloud gets substantially advanced before the ignition is commanded; this is true even if some or all the effective oxidizer is in the charge mix already. Surprise 

Consider two small explosive charges of one of the faster-burning explosives, in a binary device with stabilized liquid acetylene and liquid ozone... Wink

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