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david, for erosion control, we used to cover the landscape with old dead carpet. an interesting side effect was nothing would grow underneath it. herbicides, i haven't fooled with for thirty years, but they used to be leaf specific (broadleaf or narrow), and would dissipate shortly after use. unless they harmed ozone or something, they might still be available. a lot of stuff we're forced to use these days, either doesn't work or has undesirable side effects.
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