End caps are canted; they have nothing to do with the bearing structure itself, which is not canted. Do not be fooled by pictures you may see on the Web of locomotives with canted drivers; they are fantasy. There is no particular point in providing negative camber to the wheels themselves; that is done by coning the tread when desired.
Yes, having the 'cant' provides additional oil reservoir area at the 'bottom', where it is more needed.
Something else to note about those centipede axles is that they are not rigidly aligned in their pedestals. In between the axlebox and the little double spring going to the equalizing levers is a flat 'Fabreeka' spring, made of alternating plates of metal and an elastomeric material. This allows the axles to move sideways under restoring control without compromising vertical weight bearing or suspension characteristics. If you wondered why the centipede tender tracks so very well at high speed... that's a large part of it.
(Of course, the lateral compliance is still limited, so backing the tender up on a sharp curve will still lead to wheels popping into derailment... but that's another story.)
BTW the 1947 edition of the Locomotive Cyclopedia has some fairly extensive coverage of these pedestal tenders.
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