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News Wire: Lithium-ion batteries cause fire and explosion aboard UP train

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Posted by Brian Schmidt on Friday, April 28, 2017 1:13 PM

HOUSTON — A 53-foot intermodal container aboard a Union Pacific train caught fire and exploded April 23 just north of downtown Houston. Local media reported that the container was carrying lithium-ion batteries in a train from the port of New ...

http://trn.trains.com/news/news-wire/2017/04/28-lithium-ion-batteries-cause-fire-and-explosion-aboard-up-train

Brian Schmidt, Editor, Classic Trains magazine

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Posted by edblysard on Friday, April 28, 2017 5:19 PM

Really? WowBig Smile

23 17 46 11

RME
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Posted by RME on Friday, April 28, 2017 5:21 PM

If I'm not mistaken, a key detail is missing from many news 'coverages' of this story: these were recycled Li-ion batteries, with who knows what damage and impromptu shorting opportunities.

As battery chemistry heads more and more toward the energy density of gasoline, we shouldn't be surprised to begin to see gasoline-fire levels of energy release in incidents and accidents.

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Posted by erikem on Friday, April 28, 2017 6:25 PM

Gasoline fires at least require a source of oxygen (or F2, Cl2, ClF3...) to keep burning - battery fires can produce heat even without oxygen. About the only thing worse would be solid rocket propellant and that stuff is much less likely to spontaneously start burning.

I'd rather deal with a spent nuclear fuel cask than a container full of recycled Li-ion batteries.

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Posted by Deggesty on Friday, April 28, 2017 7:11 PM

Perhaps recycled lithium batteries should be reclassified as explosive?

Johnny

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Posted by erikem on Friday, April 28, 2017 8:33 PM

They're more like the material used in oxygen generators as in the stuff that brought down an airliner over Florida about 20 years ago. Energetic material may be a better name.

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Posted by caldreamer on Friday, April 28, 2017 8:45 PM

I just checked my copy of the hazardous materials table and all lithium batteries are classified as class 9 Miscellaneous.

A better classification might be class 4.2 - Spontaneously combustible materials - pyrophoric or self-heating materials which lithium batteries appear to be.

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Posted by Deggesty on Friday, April 28, 2017 8:56 PM

caldreamer

I just checked my copy of the hazardous materials table and all lithium batteries are classified as class 9 Miscellaneous.

A better classification might be class 4.2 - Spontaneously combustible materials - pyrophoric or self-heating materials which lithium batteries appear to be.

 

That sounds right to me, especially for used batteries..

Johnny

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Posted by edblysard on Friday, April 28, 2017 10:18 PM
Could have been worst…leaving Englewood, there are two choices to go west, one through old Hardy Yard, and the “passenger main” which runs past where the old SP Grand Central was.
Both tracks meet back up at Chaney junction.
But the passenger main also runs under the University of Houston, Downtown campus in the old Merchants and Manufactures building, and UP runs freight though there all the time when the freight main gets backed up.

 

Would have been quite a bigger show if this car had managed to be parked under the school.

23 17 46 11

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Posted by blue streak 1 on Saturday, April 29, 2017 1:23 AM

caldreamer

I just checked my copy of the hazardous materials table and all lithium batteries are classified as class 9 Miscellaneous.

A better classification might be class 4.2 - Spontaneously combustible materials - pyrophoric or self-heating materials which lithium batteries appear to be.

Our copy is not easily available right now but that does appear close.  As we know airlines have jumped ahead of the Haz Mat  book and virtually banned them.  Think motorized skate boards.

In the meantime just throwing LI-ION batteries into the recycle bin appears foolish.  Our belief is that they should be packed same way new batteries are packed not hap-hazzard.

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Posted by Deggesty on Saturday, April 29, 2017 7:55 AM

blue streak 1

 

 
caldreamer

I just checked my copy of the hazardous materials table and all lithium batteries are classified as class 9 Miscellaneous.

A better classification might be class 4.2 - Spontaneously combustible materials - pyrophoric or self-heating materials which lithium batteries appear to be.

 

 

Our copy is not easily available right now but that does appear close.  As we know airlines have jumped ahead of the Haz Mat  book and virtually banned them.  Think motorized skate boards.

In the meantime just throwing LI-ION batteries into the recycle bin appears foolish.  Our belief is that they should be packed same way new batteries are packed not hap-hazzard.

 

Hmm--not being familiar with these batteries, I wonder if contact can be made between terminals if they are simply tossed into a recycle bin and current then begins to flow from battery to battery.

Johnny

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Posted by Firelock76 on Saturday, April 29, 2017 9:05 AM

Hey, I've got an idea!  (Oh my God, NOW what!) they all said!

If they're such flamers how about recycled lithium-ion batteries as an alternative steam locomotive fuel source?  Sure, just toss a bunch of 'em in the firebox and you're ready to go!  Keeps 'em out of landfills too!  Steam tourist railroads could set themselves up as battery recycling centers and get the fuel for free!

And edblysard, LOVE your updated avatar!  Anyone tell you you're a dead-ringer for that gallant soldier and Christian gentleman General Robert E. Lee?  You should walk into a Civil War re-enactment and see what kind of reaction you get!

RME
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Posted by RME on Saturday, April 29, 2017 11:31 AM

Firelock76
If they're such flamers how about recycled lithium-ion batteries as an alternative steam locomotive fuel source? Sure, just toss a bunch of 'em in the firebox and you're ready to go!

Following that logic, why not eliminate the tiresome steps needed to ignite the things, and go straight to IRFNA and asymmetrical hydrazine as an alternative steam locomotive fuel source.  Probably comparable toxicity in the exhaust and no need to deal with those annoying leftover half-melted casings.

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Posted by samfp1943 on Saturday, April 29, 2017 12:13 PM

edblysard

Really? WowBig Smile

                       Said Ed !

"Big badda boom"

Posted by edblysard on Monday, April 24, 2017 5:51 PM

https://www.click2houston.com/news/train-catches-fire-in-ne-houston

 

"the old Hardy Street yards and round house were, just east of the old SP Grand Central."

 

         WhistlingIgnore the messenger at your own peril!  Smile, Wink & Grin

    Bang Head Sometimes, It makes you wonder WHO is paying attention?

 

 


 

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Posted by MikeF90 on Saturday, April 29, 2017 4:08 PM

RME
Following that logic, why not eliminate the tiresome steps needed to ignite the things, and go straight to IRFNA and asymmetrical hydrazine as an alternative steam locomotive fuel source.

In other news, UP has recently announced that the 4014 steam engine will be sponsored by Samsung and repowered by recycled Note 7 batteries .... Whistling

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Posted by Firelock76 on Saturday, April 29, 2017 5:14 PM

Hydrazine?  Isn't that the stuff Dr. McCoy accidentally injected himself with and went psycho on that great classic "Star Trek" episode "City On The Edge Of Forever?"

One of the best, if not THE best episode ever!

Oh, 'scuse me, that was cordrazine.  As Emily Litella used to say, "Never mind!"

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Posted by Miningman on Saturday, April 29, 2017 5:39 PM

1967- Written by Harlan Ellison! Starring a very young Joan Collins.

Famous for it's last line : Kirk says, exasperated and slowly, "Lets get the hell out of here"

Superbly written, haunting scenes. Have it on my now antique laser disc collection. Few these days even know what they are. The player itself starts up like a Turbotrain. Love it. 

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Posted by GERALD L MCFARLANE JR on Saturday, April 29, 2017 7:17 PM

blue streak 1

 

 
caldreamer

I just checked my copy of the hazardous materials table and all lithium batteries are classified as class 9 Miscellaneous.

A better classification might be class 4.2 - Spontaneously combustible materials - pyrophoric or self-heating materials which lithium batteries appear to be.

 

 

Our copy is not easily available right now but that does appear close.  As we know airlines have jumped ahead of the Haz Mat  book and virtually banned them.  Think motorized skate boardboards.

~snip~ 

First off, your statement about the airlines is not quite correct...motorized skateboards are fine, hoverboards(which have been known to catch fire) are forbidden.   Also, it's not the airlines that have rules against li-ion batteries, it's the FAA, there are specific regulations as to what kind and how many are allowed in carry-on and checked baggage, this information is available from the FAA and airlines(and probably from the TSA as well).  The FAA restrictions are based on watt hour output and that is how they're classified, it also mentions how they're transported and that they need to be kept from shorting out.

There's also the fact that Li-ion batteries come in many different forms, with the lithium being combined with among other things:

Types of lithium-ion batteries
Chemical nameMaterialShort form
Lithium Iron Phosphate1 LiFePO4 Li-phosphate
Lithium Nickel Manganese Cobalt Oxide1, also lithium-manganese-cobalt-oxide LiNiMnCoO2 (10–20% Co) NMC
Lithium Nickel Cobalt Aluminum Oxide1 LiNiCoAlO2 9% Co) NCA
Lithium Titanate2 Li4Ti5O12 Li-titanate
2 more rows
I believe the Lithium-Nickel-Manganese are the safest form, but they are also the hardest to manufacture from what I recall.

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